Composition comprising 2,3-diamino-6,7-dihydro-1h,5h-pyrazolo[1,2-a]pyrazol-1-one, 4,5-diamino-1-(b-hydroxyethyl)pyrazole and 2-chloro-6-methyl-3-aminophenol, kits containing said composition, and process for dyeing therewith

ABSTRACT

The present disclosure relates to a composition for dyeing keratin fibers, comprising, in a suitable medium, at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof; at least one second oxidation base chosen from 4,5-diamino-1-(3-hydroxyethyl)pyrazole and the addition salts thereof; and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol and the addition salts thereof. The present disclosure also relates to a process for dyeing keratin fibers using the composition of the present disclosure, the use of this composition for dyeing keratin fibers, and also a method for making the composition of the present disclosure.

This application claims benefit of U.S. Provisional Application No.61/115,649, filed Nov. 18, 2008, the contents of which are incorporatedherein by reference. This application also claims benefit of priorityunder 35 U.S.C. §119 to French Patent Application No. FR 0857539, filedNov. 6, 2008, the contents of which are also incorporated herein byreference.

The present disclosure relates to a composition for dyeing keratinfibers, for example human keratin fibers such as the hair, comprising2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or theaddition salts thereof as the at least one first oxidation base,4,5-diamino-1-(β-hydroxyethyl)pyrazole and/or the addition salts thereofas the at least one second oxidation base, and2-chloro-6-methyl-3-aminophenol and/or the addition salts thereof as theat least one coupler.

It is known practice to dye keratin fibers, for example human keratinfibers such as the hair, with dye compositions containing oxidation dyeprecursors such as ortho- or para-phenylenediamines, ortho- orpara-aminophenols, and heterocyclic compounds such as diaminopyrazolederivatives, pyrazolo[1,5-a]pyrimidine derivatives, pyrimidinederivatives, pyridine derivatives, indole derivatives and indolinederivatives, which are generally known as oxidation bases. Oxidation dyeprecursors, or oxidation bases, are colorless or weakly coloredcompounds which, when combined with oxidizing products, can give rise tocolored or coloring compounds via a process of oxidative condensation.Permanent colorations may thus be obtained.

It is also known that the shades obtained with these oxidation bases maybe varied by combining them with couplers or coloration modifiers, thelatter being chosen for example from meta-phenylenediamines,meta-aminophenols, meta-hydroxyphenols and certain heterocycliccompounds.

The variety of molecules used as regards the oxidation bases andcouplers allows a wide range of colors to be obtained.

The use of oxidation bases such as para-phenylenediamine andpara-aminophenol derivatives can allow quite a broad range of colors tobe obtained at basic pH, but may not always, however, simultaneouslyachieve shades with good chromaticity, while at the same time giving thehair excellent properties in terms of strength of color, uniformity ofthe color, and fastness with respect to external agents.

The use of these bases at neutral pH does not always allow a variedrange of shades to be produced, for example warm shades such as reds andoranges.

Thus there is a need in the art to provide novel compositions for dyeingkeratin fibers that make it possible to obtain a coloration with atleast one of the following attributes: strong, powerful, chromatic,aesthetic, and sparingly selective red and/or coppery shades, and forexample intermediate reddish-copper and coppery-red shades, showing goodresistance to the various attacking factors to which the hair may besubjected, such as shampoos, light, sweat, and permanent-wave reshapingoperations.

The present disclosure therefore relates to a composition for dyeingkeratin fibers, comprising, in a suitable medium:

-   -   at least one first oxidation base chosen from        2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one of        formula (I) and the addition salts thereof:

-   -   at least one second oxidation base chosen from        4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts        thereof; and    -   at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol        and the addition salts thereof.

The present disclosure can make it possible to obtain coloring of thekeratin fibers in strong and/or chromatic red and/or coppery shades. Theintermediate coppery-red and reddish-copper shades obtained can beaesthetic with great strength and/or chromaticity.

The present disclosure can also make it possible to obtain sparinglyselective colorations that show good resistance to the various attacksto which the hair may be subjected, such as shampoos, light, sweat, andpermanent-wave reshaping operations. It furthermore can also make itpossible to obtain strong colorations at neutral pH.

The present disclosure also relates to a process for dyeing keratinfibers using the composition of the present disclosure, the use of thiscomposition for dyeing keratin fibers, and also a method for making thecomposition of the present disclosure.

The present disclosure also relates to a dyeing kit comprising, in afirst compartment, a dye composition containing2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or a saltthereof as the at least one first oxidation base,4,5-diamino-1-β-hydroxyethyl)pyrazole and/or a salt thereof as the atleast one second oxidation base, and 2-chloro-6-methyl-3-aminophenoland/or a salt thereof as the at least one coupler, and, in a secondcompartment, a composition containing at least one oxidizing agent.

According to at least one embodiment, in the composition in accordancewith the disclosure, the molar ratio of the amount of the at least onecoupler to the total amount of the combination of the at least one firstoxidation base and the at least one second oxidation base has a value ofless than or equal to 1, for example ranging from 0.05 to 1, such asfrom 0.1 to 0.8.

The compositions of the disclosure may contain the at least one firstoxidation base and/or the at least one second oxidation base,respectively, in the form of a mixture of several salts or of a mixtureof a nonsalified compound with at least one salt.

Unless otherwise indicated, the limits of the ranges of values which aregiven in the context of the present disclosure are included in theseranges.

The dye composition of the disclosure may contain at least oneadditional oxidation base that is different from the at least one firstand the at least one second oxidation bases chosen from thoseconventionally used for dyeing keratin fibers.

The composition of the present disclosure may, for example, comprise atleast one additional oxidation base chosen from para-phenylenediamines,bis(phenyl)alkylenediamines, para-aminophenols, bis-para-aminophenols,ortho-aminophenols, ortho-phenylenediamines and heterocyclic bases otherthan 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one,4,5-diamino-1-(β-hydroxyethyl)pyrazole, and the addition salts thereof.

Among the para-phenylenediamines, non-limiting mention may be made, byway of example, of para-phenylenediamine, para-toluenediamine,2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine,2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine,2,5-dimethyl-para-phenylenediamine, N,N-dimethyl-para-phenylenediamine,N,N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine,4-amino-N,N-diethyl-3-methylaniline,N,N-bis(p-hydroxyethyl)-para-phenylenediamine,4-N,N-bis(β-hydroxyethyl)amino-2-methylaniline,4-N,N-bis(β-hydroxyethyl)amino-2-chloroaniline,2-3-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine,2-isopropyl-para-phenylenediamine,N-(β-hydroxypropyl)-para-phenylenediamine,2-hydroxymethyl-para-phenylenediamine,N,N-dimethyl-3-methyl-para-phenylenediamine,N,N-(ethyl-β-hydroxyethyl)-para-phenylenediamine,N-β,γ-dihydroxypropyl)-para-phenylenediamine,N-(4′-aminophenyl)-para-phenylenediamine,N-phenyl-para-phenylenediamine,2-β-hydroxyethyloxy-para-phenylenediamine,2-β-acetylaminoethyloxy-para-phenylenediamine,N-(p-methoxyethyl)-para-phenylenediamine, 4-aminophenylpyrrolidine,2-thienyl-para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene,3-hydroxy-1-(4′-aminophenyl)pyrrolidine, and the addition salts thereof.

Among the para-phenylenediamines mentioned above, non-limiting mentionmay also be made of para-phenylenediamine, para-toluenediamine,2-isopropyl-para-phenylenediamine,2-β-hydroxyethyl-para-phenylenediamine,2-β-hydroxyethyloxy-para-phenylenediamine,2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine,2,3-dimethyl-para-phenylenediamine,N,N-bis(β-hydroxyethyl)-para-phenylenediamine,2-chloro-para-phenylenediamine,2-β-acetylaminoethyloxy-para-phenylenediamine, and the addition saltsthereof.

Among the bis(phenyl)alkylenediamines, non-limiting mention may be made,by way of example, ofN,N′-bis(β-hydroxyethyl)-N,N′-bis(4′-aminophenyl)-1,3-diaminopropanol,N,N′-bis(β-hydroxyethyl)-N,N′-bis(4′-aminophenyl)ethylenediamine,N,N′-bis(4-aminophenyl)tetramethylenediamine, NN′-bis(β-hydroxyethyl)-N,N′-bis(4-aminophenyl)tetramethylenediamine,N,N′-bis(4-methyl-aminophenyl)tetramethylenediamine,N,N′-bis(ethyl)-N,N′-bis(4′-amino-3′-methylphenyl)ethylenediamine,1,8-bis(2,5-diaminophenoxy)-3,6-dioxaoctane, and the addition saltsthereof.

Among the para-aminophenols, non-limiting mention may be made, by way ofexample, of para-aminophenol, 3-methyl-4-aminophenol,4-amino-3-fluorophenol, 4-amino-3-hydroxymethylphenol,4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol,4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol,4-amino-2-(β-hydroxyethylaminomethyl)phenol, 4-amino-2-fluorophenol, andthe addition salts thereof.

Among the ortho-aminophenols, non-limiting mention may be made, by wayof example, of 2-aminophenol, 2-amino-5-methylphenol,2-amino-6-methylphenol, 5-acetamido-2-aminophenol, and the additionsalts thereof.

Among the heterocyclic bases, non-limiting mention may be made, by wayof example, of pyridine derivatives, pyrimidine derivatives, andpyrazole derivatives.

Among the pyridine derivatives, non-limiting mention may be made of thecompounds described, for example, in patents GB 1 026 978 and GB 1 153196, such as 2,5-diaminopyridine,2-(4-methoxyphenyl)amino-3-aminopyridine, 2,3-diamino-6-methoxypyridine,2-(β-methoxyethyl)amino-3-amino-6-methoxypyridine, 3,4-diamino-pyridine,and the addition salts thereof.

Other pyridine oxidation bases that may be used in the presentdisclosure for example are the 3-aminopyrazolo[1,5-a]pyridine oxidationbases, or the addition salts thereof, described for example in patentapplication FR 2 801 308. By way of example, non-limiting mention may bemade of pyrazolo[1,5-a]pyrid-3-ylamine;2-acetylaminopyrazolo[1,5-a]pyrid-3-ylamine;2-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine;3-aminopyrazolo[1,5-a]pyridine-2-carboxylic acid;2-methoxypyrazolo[1,5-a]pyrid-3-ylamine;(3-aminopyrazolo[1,5-a]pyrid-7-yl)methanol;2-(3-aminopyrazolo[1,5-a]pyrid-5-yl)ethanol;2-(3-aminopyrazolo[1,5-a]pyrid-7-yl)ethanol;(3-aminopyrazolo[1,5-a]pyrid-2-yl)methanol;3,6-diaminopyrazolo[1,5-a]pyridine; 3,4-diaminopyrazolo[1,5-a]pyridine;pyrazolo[1,5-a]pyridine-3,7-diamine;7-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine;pyrazolo[1,5-a]pyridine-3,5-diamine;5-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine;2-[(3-aminopyrazolo[1,5-a]pyrid-5-yl)(2-hydroxyethyl)amino]ethanol;2-[(3-aminopyrazolo[1,5-a]pyrid-7-yl)(2-hydroxyethyl)amino]ethanol;3-aminopyrazolo[1,5-a]pyrid-5-ol; 3-aminopyrazolo[1,5-a]pyrid-4-ol;3-aminopyrazolo[1,5-a]pyrid-6-ol; 3-aminopyrazolo[1,5-a]pyrid-7-ol; andalso the addition salts thereof.

Among the pyrimidine derivatives, non-limiting mention may be made ofthe compounds described, for example, in patents DE 23 59 399; JP88-169571; JP 05-63124; EP 0 770 375 or patent application WO 96/15765,such as 2,4,5,6-tetraaminopyrimidine,4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine,2,4-dihydroxy-5,6-diaminopyrimidine and 2,5,6-triaminopyrimidine, andpyrazolopyrimidine derivatives such as those mentioned in patentapplication FR-A-2 750 048 and among which non-limiting mention may bemade of pyrazolo[1,5-a]pyrimidine-3,7-diamine;2,5-dimethylpyrazolo[1,5-a]pyrimidine-3,7-diamine;pyrazolo[1,5-a]pyrimidine-3,5-diamine;2,7-dimethylpyrazolo[1,5-a]pyrimidine-3,5-diamine;3-aminopyrazolo[1,5-a]pyrimidin-7-ol;3-aminopyrazolo[1,5-a]pyrimidin-5-ol;2-(3-aminopyrazolo[1,5-a]pyrimidin-7-ylamino)ethanol,2-(7-aminopyrazolo[1,5-a]pyrimidin-3-ylamino)ethanol,2-[(3-aminopyrazolo[1,5-a]pyrimidin-7-yl)(2-hydroxyethyl)amino]ethanol,2-[(7-aminopyrazolo[1,5-a]pyrimidin-3-yl)(2-hydroxyethyl)amino]ethanol,5,6-dimethylpyrazolo-[1,5-a]pyrimidine-3,7-diamine,2,6-dimethylpyrazolo[1,5-a]pyrimidine-3,7-diamine,2,5,N7,N7-tetramethylpyrazolo[1,5-a]pyrimidine-3,7-diamine and3-amino-5-methyl-7-imidazolylpropylaminopyrazolo[1,5-a]pyrimidine, andthe addition salts thereof and tautomeric forms thereof, when atautomeric equilibrium exists.

Among the pyrazole derivatives, non-limiting mention may be made of thecompounds described in patents DE 38 43 892 and DE 41 33 957 and patentapplications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988such as 4,5-diamino-1-methylpyrazole, 3,4-diaminopyrazole,4,5-diamino-1-(4′-chlorobenzyl)pyrazole,4,5-diamino-1,3-dimethylpyrazole, 4,5-diamino-3-methyl-1-phenylpyrazole,4,5-diamino-1-methyl-3-phenylpyrazole,4-amino-1,3-dimethyl-5-hydrazinopyrazole,1-benzyl-4,5-diamino-3-methylpyrazole,4,5-diamino-3-test-butyl-1-methylpyrazole,4,5-diamino-1-tert-butyl-3-methylpyrazole,4,5-diamino-1-(13-hydroxyethyl)-3-methylpyrazole,4,5-diamino-1-ethyl-3-methylpyrazole,4,5-diamino-1-ethyl-3-(4′-methoxyphenyl)pyrazole,4,5-diamino-1-ethyl-3-hydroxymethylpyrazole,4,5-diamino-3-hydroxymethyl-1-methylpyrazole,4,5-diamino-3-hydroxymethyl-1-isopropylpyrazole,4,5-diamino-3-methyl-1-isopropylpyrazole,4-amino-5-(2′-aminoethyl)amino-1,3-dimethylpyrazole,3,4,5-triaminopyrazole, 1-methyl-3,4,5-triaminopyrazole,3,5-diamino-1-methyl-4-methylaminopyrazole,3,5-diamino-4-(β-hydroxyethyl)amino-1-methylpyrazole, the addition saltsthereof.

In at least one embodiment of the present disclosure, the compositiondisclosed herein comprises at least one additional oxidation base chosenfrom para-aminophenols and para-phenylenediamines. For example, amongthe para-aminophenols, para-aminophenol, 3-methyl-4-aminophenol, and theaddition salts thereof can be used. For instance, among thepara-phenylenediamines, para-phenylenediamine, para-toluenediamine,N,N-bis(β-hydroxyethyl)-para-phenylenediamine, and the addition saltsthereof can be used.

The dye composition of the disclosure may contain at least oneadditional coupler that is different from the at least one couplerchosen from 2-chloro-6-methyl-3-aminophenol and the addition saltsthereof conventionally used for dyeing keratin fibers.

The composition of the present disclosure may, for example, thuscomprise at least one additional coupler chosen frommeta-phenylenediamines, meta-aminophenols that are different from2-chloro-6-methyl-3-aminophenol and the addition salts thereof,meta-diphenols, naphthalene couplers, heterocyclic couplers, and/or theaddition salts thereof.

By way of example of the at least one additional coupler, non-limitingmention may be made of 3-aminophenol, 2-methyl-5-aminophenol,1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene,4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1-(β-hydroxyethyloxy)benzene,2-amino-4-(13-hydroxyethylamino)-1-methoxybenzene, 1,3-diaminobenzene,1,3-bis(2,4-diaminophenoxy)propane, 3-ureidoaniline,3-ureido-1-dimethylaminobenzene, sesamol,1-13-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol,2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole,4-hydroxy-N-methylindole, 2-amino-3-hydroxypyridine,6-hydroxybenzomorpholine, 3,5-diamino-2,6-dimethoxypyridine,1-N-(β-hydroxyethypamino-3,4-methylenedioxybenzene,2,6-bis([3-hydroxyethylamino)toluene, and the addition salts thereof.

In at least one embodiment, the composition in accordance with thedisclosure comprises at least one additional coupler chosen frommeta-aminophenols different from the at least one coupler chosen from2-chloro-6-methyl-3-aminophenol and the addition salts thereof. Forexample, the composition in accordance with the disclosure may compriseat least one additional coupler chosen from 2-methyl-5-aminophenol,2-methyl-5-(β-hydroxyethylamino)phenol, and the addition salts thereof.

The at least one first oxidation base, the at least one second oxidationbase, and the at least one additional oxidation base may each be presentin the composition of the disclosure in an amount ranging from 0.001% to10% by weight, relative to the total weight of the dye composition, suchas from 0.005% to 6%.

The at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol andthe addition salts thereof, and the at least one additional coupler mayeach be present in the composition of the disclosure in an amountranging from 0.001% to 10% by weight, relative to the total weight ofthe dye composition, such as from 0.005% to 6%.

In general, the addition salts of the oxidation bases and of thecouplers that can be used in the context of the disclosure are forexample chosen from the addition salts with an acid, such as thehydrochlorides, hydrobromides, sulfates, citrates, succinates,tartrates, lactates, (C₁-C₄)alkylsulfonates, and for examplemethylsulfonates, tosylates, benzenesulfonates, phosphates and acetates,and the addition salts with a base, such as sodium hydroxide, potassiumhydroxide, aqueous ammonia, amines or alkanolamines.

The medium that is suitable for dyeing, also known as a dye support, isa cosmetic medium generally constituted of water or of a mixture ofwater and at least one organic solvent. By way of organic solvent,non-limiting mention may, for example, be made of C₁-C₄ lower alkanols,such as ethanol and isopropanol; polyols and polyol ethers such as2-butoxyethanol, propylene glycol, propylene glycol monomethyl ether,diethylene glycol monoethyl ether and diethylene glycol monomethylether, and also aromatic alcohols such as benzyl alcohol orphenoxyethanol, and mixtures thereof.

The solvents may for example be present in an amount ranging from 1% to40% by weight, relative to the total weight of the dye composition, andfor example from 5% to 30% by weight.

The dye composition in accordance with the disclosure may also containat least one adjuvant chosen from the various adjuvants conventionallyused in compositions for dyeing the hair, such as anionic, cationic,nonionic, amphoteric or zwitterionic surfactants or mixtures thereof,anionic, cationic, nonionic, amphoteric or zwitterionic polymers ormixtures thereof, inorganic or organic thickeners, and for exampleanionic, cationic, nonionic and amphoteric associative polymericthickeners, antioxidants, penetrating agents, sequestering agents,fragrances, buffers, dispersing agents, conditioning agents, such as forexample silicones, which may be volatile or non-volatile, and modifiedor unmodified, film-forming agents, ceramides, preservatives, andopacifiers.

The at least one adjuvant may be present in an amount, for eachadjuvant, ranging from 0.01% to 20% by weight, relative to the weight ofthe dye composition.

Of course, those skilled in the art will take care to select this orthese optional additional compound(s) in such a way that the beneficialproperties intrinsically associated with the oxidation dye compositionin accordance with the disclosure are not, or are not substantially,impaired by the addition(s) envisaged.

The pH of the dye composition in accordance with the disclosuregenerally ranges from 3 to 12, for example from 5 to 11. It may beadjusted to the desired value using acidifying or basifying agentsnormally used in the dyeing of keratin fibers, or alternatively usingstandard buffer systems.

Among the acidifying agents, non-limiting mention may be made, by way ofexample, of inorganic or organic acids such as hydrochloric acid,orthophosphoric acid, sulfuric acid, carboxylic acids such as aceticacid, tartaric acid, citric acid or lactic acid, and sulfonic acids.

Among the basifying agents, non-limiting mention may be made, by way ofexample, of aqueous ammonia, alkali metal carbonates, alkanolamines suchas mono-, di- and triethanolamines and also derivatives thereof, sodiumhydroxide, potassium hydroxide and the compounds of formula (II) below:

in which W is a propylene residue optionally substituted with a hydroxylgroup or a C₁-C₄ alkyl radical; and R_(a), R_(b), R_(c) and R_(d), whichmay be identical or different, represent a hydrogen atom, a C₁-C₄ alkylradical, or a C₁-C₄ hydroxyalkyl radical.

The dye composition according to the disclosure may be in various forms,such as in the form of liquids, creams, or gels, or in any other formthat is suitable for dyeing keratin fibers such as human hair.

The present disclosure also relates to a process for dyeing keratinfibers, comprising:

applying to the keratin fibers a composition comprising, in a suitablemedium,

-   -   at least one first oxidation base chosen from        2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and        the addition salts thereof;    -   at least one second oxidation base chosen from        4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts        thereof; and    -   at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol        and the addition salts thereof;

in the presence of at least one oxidizing agent; and

leaving the resultant composition on the keratin fibers for a period oftime that is sufficient to develop the desired coloration. The color isdeveloped using the at least one oxidizing agent. The color may bedeveloped at acidic, neutral, or alkaline pH and the at least oneoxidizing agent may be added to the composition of the disclosure justat the time of use, or it may be used starting from an oxidizingcomposition containing it, which is applied simultaneously with orsequentially to the composition of the disclosure.

According to at least one embodiment, the composition according to thepresent disclosure is mixed, for example at the time of use, with acomposition containing, in a medium that is suitable for dyeing, atleast one oxidizing agent, the at least one oxidizing agent beingpresent in an amount that is sufficient to develop a coloration. The“ready-to-use” mixture obtained is then applied to the keratin fibers.After a leave-in time ranging from 3 to 50 minutes, for example 5 to 30minutes, the keratin fibers are rinsed, washed with shampoo, rinsedagain, and then dried.

The oxidizing agents conventionally used for the oxidation dyeing ofkeratin fibers are, for example, hydrogen peroxide, urea peroxide,alkali metal bromates, persalts such as perborates and persulfates,peracids and oxidase enzymes, among which non-limiting mention may bemade of peroxidases, 2-electron oxidoreductases such as uricases, and4-electron oxygenases such as laccases. For example, hydrogen peroxidecan be used in at least one embodiment.

The oxidizing composition may also contain at least one adjuvant chosenfrom the various adjuvants conventionally used in compositions fordyeing the hair and as defined herein.

The pH of the oxidizing composition containing the at least oneoxidizing agent is such that, after mixing with the dye composition, thepH of the resulting composition applied to the keratin fibers forexample can range from 3 to 12, such as from 5 to 11. It may be adjustedto the desired value via acidifying or basifying agents normally used inthe dyeing of keratin fibers and as defined herein.

The ready-to-use composition that is applied to the keratin fibers maybe in various forms, such as in the form of liquids, creams, or gels, orany other form suitable for dyeing keratin fibers such as human hair.

The present disclosure is also relates to a multi-compartment dyeingdevice or “kit,” in which a first compartment contains the dyecomposition of the present disclosure as defined herein with theexception of the at least one oxidizing agent, and a second compartmentcontains an oxidizing composition. This device may be equipped with anapplicator for applying the desired mixture to the hair, such as thedevices described in patent FR-2 586 913. The multi-compartment devicefor dyeing keratin fibers thus comprises:

-   -   a first compartment containing a dye composition, comprising, in        a suitable medium:        -   at least one first oxidation base chosen from            2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one            and the addition salts thereof;        -   at least one second oxidation base chosen from            4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition            salts thereof; and        -   at least one coupler chosen from            2-chloro-6-methyl-3-aminophenol and the addition salts            thereof;    -   and    -   a second compartment containing at least one oxidizing agent.

The present disclosure also relates to a method for making a compositionfor dyeing keratin fibers comprising, combining, in a suitable medium:

-   -   at least one first oxidation base chosen from        2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and        the addition salts thereof;    -   at least one second oxidation base chosen from        4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts        thereof; and    -   at lest one coupler chosen from 2-chloro-6-methyl-3-aminophenol        and the addition salts thereof,    -   wherein the ingredients can be added in any order.

The examples which follow serve to illustrate the disclosure without,however, being limiting in nature.

EXAMPLE 1

The following dye composition was prepared (amounts expressed withrespect to the total weight of the composition, unless otherwiseindicated):

Lauryl alcohol comprising 12 EO 7 g Decyl alcohol comprising 3 EO 10 gOleocetyl alcohol comprising 30 EO 4 g Cetylstearyl alcohol 11.5 gLauric acid 3 g Glycol distearate 2 g AEROSIL R 972 (Degussa) 1.2 gCARBOPOL 980 (Lubrizol) 0.4 g Propylene glycol 10 g Monoethanolamine 1.6g MEXOMERE PO (Chimex) 3 g AM MERQUAT 280 (Nalco) 2.2 g AM Sequesteringagent, antioxidant, reducing agent, q.s. fragrance Aqueous ammonia (20%of NH₃) 10 g 2,3-diamino-6,7-dihydro-1H,5H- 0.3 gpyrazolo[1,2-a]pyrazol-1-one, 2 CH₃—SO₃H4,5-diamino-1-(β-hydroxyethyl)pyrazole, sulfate 1.7 g2-chloro-6-methyl-3-aminophenol 0.3 g Para-phenylenediamine 0.42 gPara-aminophenol 0.2 g 2-methyl-5-aminophenol 1.4 g Water q.s. 100 g AM= Active material

At the time of use, 1 part by weight of the Example 1 dye compositionwas mixed with 1.5 parts by weight of a 20-volumes hydrogen peroxidesolution at pH 2.2. A final pH close to 9.6 was obtained.

The mixture obtained was applied to locks of grey hair containing 90%white hairs. After a leave-on time of 30 minutes at ambient temperature,the locks were rinsed, washed with a standard shampoo, rinsed again andthen dried.

The hair coloration was evaluated visually. A sparingly selective,chromatic, coppery-red blonde shade was obtained.

EXAMPLE 2

The following dye composition was prepared (amounts expressed withrespect to the total weight of the composition, unless otherwiseindicated):

Lauryl alcohol comprising 12 EO 7 g Decyl alcohol comprising 3 EO 10 gOleocetyl alcohol comprising 30 EO 4 g Cetylstearyl alcohol 11.5 gLauric acid 3 g Glycol distearate 2 g AEROSIL R 972 (Degussa) 1.2 gCARBOPOL 980 (Lubrizol) 0.4 g Propylene glycol 10 g Monoethanolamine 1.6g MEXOMERE PO (Chimex) 3 g AM MERQUAT 280 (Nalco) 2.2 g AM Sequesteringagent, antioxidant, reducing agent, q.s. fragrance Aqueous ammonia (20%of NH₃) 10 g 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2- 0.3 ga]pyrazol-1-one, 2 CH₃—SO₃H 4,5-diamino-1-(β-hydroxyethyl)pyrazole,sulfate 1.7 g 2-chloro-6-methyl-3-aminophenol 0.3 g2-methyl-5-aminophenol 1.0 g Water q.s. 100 g AM = Active material

1. A composition for dyeing keratin fibers, comprising, in a suitablemedium: at least one first oxidation base chosen from2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and theaddition salts thereof; at least one second oxidation base chosen from4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts thereof;and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol andthe addition salts thereof.
 2. A composition according to claim 1,wherein the molar ratio of the amount of the at least one coupler, tothe total amount of the combination of the at least one first oxidationbase and the at least one second oxidation base has a value of less thanor equal to
 1. 3. A composition according to claim 1, further comprisingat least one additional oxidation base chosen from para-aminophenols andpara-phenylenediamines.
 4. A composition according to claim 3, whereinthe at least one additional oxidation base is chosen frompara-aminophenol, 3-methyl-4-aminophenol, and the addition saltsthereof.
 5. A composition according to claim 3, wherein the at least oneadditional oxidation base is chosen from para-phenylenediamine,para-toluenediamine, N,N-bis(β-hydroxyethyl)-para-phenylenediamine, andthe addition salts thereof.
 6. A composition according to claim 1,further comprising at least one additional coupler.
 7. A compositionaccording to claim 6, wherein the at least one additional coupler ischosen from 2-methyl-5-aminophenol,2-methyl-5-(β-hydroxyethylamino)phenol, and the addition salts thereof.8. A composition according to claim 1, wherein the at least one firstoxidation base and the at least one second oxidation base are eachpresent in an amount ranging from 0.001% to 10% by weight, relative tothe total weight of the composition.
 9. A composition according to claim1, wherein the at least one coupler is present in an amount, for eachcoupler, ranging from 0.001% to 10% by weight, relative to the totalweight of the composition.
 10. A composition according to claim 1,further comprising at least one oxidizing agent.
 11. A process fordyeing keratin fibers, comprising: applying to the keratin fibers acomposition comprising, in a suitable medium, at least one firstoxidation base chosen from2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and theaddition salts thereof; at least one second oxidation base chosen from4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts thereof;and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol andthe addition salts thereof; in the presence of at least one oxidizingagent; and leaving the resultant composition on the keratin fibers for aperiod of time that is sufficient to develop the desired coloration. 12.A multi-compartment device for dyeing keratin fibers, comprising a firstcompartment containing a dye composition comprising, in a suitablemedium: at least one first oxidation base chosen from2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and theaddition salts thereof; at least one second oxidation base chosen from4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts thereof;and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol andthe addition salts thereof; and a second compartment containing at leastone oxidizing agent.
 13. A method for making a composition for dyeingkeratin fibers comprising combining, in a suitable medium: at least onefirst oxidation base chosen from2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and theaddition salts thereof; at least one second oxidation base chosen from4,5-diamino-1-(β-hydroxyethyl)pyrazole and the addition salts thereof;and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol andthe addition salts thereof, wherein the ingredients can be added in anyorder.